6,6-ionene-stabilized gold nanoparticles: synthesis, characterization and prospects of use

Tóm tắt

Synthesis of new polycation-stabilized gold nanoparticles was performed by the borohydride approach. 6,6-ionene was used as a polycationic stabilizer. The influence of several factors such as the acidity, the Au:ionene ratio and the concentration of sodium borohydride during the synthesis were investigated. The key role of the amount of HCl added during the synthesis on the behaviour of the products in time was shown. Optimal conditions for the synthesis were chosen. The prepared gold nanoparticles were characterized by surface plasmon resonance band at 520 nm. Their average diameter is 16 nm. Apart from spherical (73%), there were pentagonal (14%), hexagonal (7%), triangular (4%) and cylindrical (2%) nanoparticles. These particles were stable in solution for at least four month.s Aggregative stability of the nanoparticles in the presence of different inorganic anions was tested. It was shown that the most aggregative effect was produced by sulfate, which reveals the prospects for use of ionene-stabilized gold nanoparticles for the selective detection of sulfate. These nanoparticles can be easily adsorbed on hydrophobic C8-silica, which may offer the way to new solid-phase nanomaterials for recovering and separation.

Từ khoá

gold nanoparticles, ionene, surface plasmon resonance, synthesis, characterization, analytical application

Tài liệu tham khảo

Dykman L A and Bogatyrev V A 2007 Russ. Chem. Rev. 76 181
Algar W R, Massey M and Krull U J 2009 Trends Anal. Chem. 28 292
Dreaden E C, Alkilany A M, Huang X, Murphy C J and El S M A 2012 Chem. Soc. Rev. 41 2740
Nguyen D T, Kim D J and Kim K S 2011 Micron 42 207–27
Jans H and Huo Q 2012 Chem. Soc. Rev. 41 2849
Agasti S S, Rana S, Park M H, Kim C K, You C C and Rotello V M 2010 Adv. Drug. Deliver. Rev. 62 316
Wang Z 2009 Coord. Chem. Rev. 253 1607
Yong K T, Swihart M T, Ding H and Prasad P N 2009 Plasmonics 4 79
Pissuwan D, Cortie C H, Valenzuela S M and Cortie M B 2010 Trends Biotechnol. 28 207
Guo S J and Wang E K 2007 Anal. Chim. Acta 598 181
Vertelov G K, Olenin A Y and Lisichkin G V 2007 J. Anal. Chem. 62 813
Nilsson C, Birnbaum S and Nilsson S 2007 J. Chromatogr. A 1168 212
Sykora D, Miksik I, Rezanka P, Zaruba K, Matejka P and Kral V 2010 J. Sep. Sci. 33 372
Shtykov S N and Rusanova T Y 2008 Ros. Khim. Zh. 52 92 (in Russian)
Saha K, Agasti S S, Kim C, Li X and Rotello V M 2012 Chem. Rev. 112 2739
Guo S and Dong S 2009 Trends Anal. Chem. 28 96
Mayer K M and Hafner J H 2011 Chem. Rev. 111 3828
Upadhyayula V K K 2012 Anal. Chim. Acta 715 1
Ghosh S K and Pal T 2007 Chem. Rev. 107 4797
Saarinen J J, Vartiainen E M and Peiponen K E 2009 Sensors Actuators B 138 383
Apyari V V, Arkhipova V V, Dmitrienko S G and Zolotov Y A 2014 J. Anal. Chem. 69 1
Pirogov A V, Platonov M M and Shpigun O A 1999 J. Chromatogr. A 850 53
Pirogov A V, Krokhin O V, Platonov M M, Deryugina Y I and Shpigun O A 2000 J. Chromatogr. A 884 31
Mikhalyuk A N, Shapovalova E N, D’yachkov I A, Apanasenko N V, Prokhorova A F, Aksenov A S, Bogolitsin K G and Shpigun O A 2013 J. Anal. Chem. 68 450
Mikhalyuk A N, Shapovalova E N, Maguga A G, Shpigun O A and Rudakovskaja P G 2013 Moscow Univ. Chem. Bull. 68 219

Các bài trích dẫn đến

1. Ekaterina A Terenteva, Viktoria V Arkhipova, Vladimir V Apyari, Pavel A Volkov, Stanislava G Dmitrienko. Simple and rapid method for screening of pyrophosphate using 6, 6-ionene-stabilized gold and silver nanoparticles in Sensors and Actuators B: Chemical (Vol. 241, 2017)
2. AV Ivanov, AA Kozlov, AN Koreshkova, SD Abdullaev, IA Fedorova. Reflectance spectra of organic matrices on the basis of photonic crystals formed of polystyrene microspheres with a particle size of 230 nm in Moscow University Chemistry Bulletin (Vol. 72, No. 1, 2017)
3. Vladimir V Apyari, Viktoria V Arkhipova, Maria V Gorbunova, Pavel A Volkov, Andrey I Isachenko, Stanislava G Dmitrienko, Yury A Zolotov. Towards the development of solid-state platform optical sensors: aggregation of gold nanoparticles on polyurethane foam in Talanta (Vol. 161, 2016)
4. Александр Вадимович Иванов, Андрей Аркадьевич Козлов, Александра Николаевна Корешкова, Собир Дилшодович Абдуллаев, Ирина Александровна Фёдорова. Спектры отражения органических матриц на основе фотонных кристаллов из полистирольных микросфер диаметром 230 нм in Вестник Московского Университета (Vol. 57, No. 6, 2016)
5. VV Apyari, SG Dmitrienko, MV Gorbunova, AA Furletov, Yu A Zolotov. Gold and Silver Nanoparticles in Optical Molecular Absorption Spectroscopy in Journal of Analytical Chemistry (Vol. 74, No. 1, 2019)
6. AV Ivanov, ES Bol’shakov, VV Apyari, AA Kozlov, MV Gorbunova, SD Abdullaev. Analytical Response of Sensor Arrays Based on Photonic Crystals: Measurements of Diffuse Reflectance in Journal of Analytical Chemistry (Vol. 74, No. 2, 2019)
8. АВ Иванов, ЕС Большаков, ВВ Апяри, АА Козлов, МВ Горбунова, СД Абдуллаев. Аналитический отклик сенсорных матриц на основе фотонных кристаллов: измерение диффузного отражения in Журнал аналитической химии (Vol. 74, No. 2, 2019)